Bis[N-(pyridin-2-ylcarbonyl)pyridine-2-carboximidato-κ3 N,N′,N′′]iron(III) tris(cyanido-κC)[N-(pyridin-2-ylcarbonyl)pyridine-2-carboximidato-κ3 N,N′,N′′]ferrate(III) monohydrate
نویسندگان
چکیده
In the title compound, [Fe(C(12)H(8)N(3)O(2))(2)][Fe(C(12)H(8)N(3)O(2))(CN)(3)]·H(2)O, the Fe(3+) ions in the cation and anion each lie in a slightly distorted octa-hedral coordination environment. The solvent water mol-ecule is disordered over three positions with occupancies of 0.401 (7), 0.322 (7) and 0.277 (6). The water content was confirmed by thermogravimetric data.
منابع مشابه
Bis[N-(pyridin-2-ylcarbonyl)pyridine-2-carboxamidato]iron(III) perchlorate monohydrate
The structure of the title salt complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·H(2)O, contains one Fe(III) cation, two N-(pyridin-2-ylcarbon-yl)pyridine-2-carboxamidate (bpca(-)) anions, one perchlorate anion and one water mol-ecule. The Fe(III) cation has an approximate octa-hedral geometry, defined by six N atoms from two bpca(-) anions. The nearly parallel [dihedral angle = 1.50 (1)°] bpca(-) ani...
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متن کاملBis[N-(8-quinolyl)pyridine-2-carboxamidato-κ3 N,N′,N′′]manganese(III) perchlorate monohydrate
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011